Inhibitors prevent polymerization in two ways. To accomplish this, the design and construction of a satisfactory bulk storage system for styre ne requires careful consideration to eliminate ex cessive temperatures and to prevent contamination with polymer from infrequently used lines and other equipment. Prevention of colo r formation is also important, but this is normally caused by contaminatio n such as rust. For more information, refer to OSHA Standard 2 9 CFR , Flammable and Co mbustible Liquids, National Fire Protection Association (NFPA) 77, Recommended Practice on Static Electricity and/or the A merican Petroleum Institute (API) Recommended Practice 2003, Protection Against Ignitions Arising Out of Static, Lightning, and Stray Currents. 6. 10 to 15 days 1 year 85 F 3 mo. ), Vol. Eng. Interzinc 98 Matcote Co. 2. Raise it at such a rate that it i s about three fourths full when it emerges from the liq uid. III. Static Electricity. For large fires, water spray or fog may be effective. A Health and Safety Guideline for Your Workplace. 4 to 5 days 6 months 110 F 8 to 12 days Less than 24 hours Less than 30 days Table 2A Suggested Monitoring Schedule for Styrene Bulk Storage Monomer Temperature Daily Table 2B Suggested Testing Schedule for Styrene Bulk Storage Monomer Temperature, degrees F 80 or higher Below 70 Frequency Weekly Bi-weekly Monthly Polymer Inhibitor Color Appearance Aldehydes Peroxides Key Properties ASTM D2121 ASTM D4590 ASTM D5386 or D1209 Visual ASTM D2119 ASTM D2340 JULY 2011 (PRINT) 15, 21 Table 2C Suggested Inspection Schedule for Styrene Bulk Storage Inspection Air Vents Vacuum pressure relief Flame arrester Foam reservoir should be inspected for polymer Tank interior Frequency Quarterly Every 3 years, if coated Annually, if uncoated OXYGEN REQUIREMENTS The problem presented by air i s complex. 4. Keep vessel vented. 1, Am. Signs and symptoms of styrene exposure and action to be ta ken and medical conditions aggravated by exposure to styrene. PRODUCT IDENTIFIER Carbon Dioxide, Refrigerated Liquid, #158 PURE SYNTHETIC COMPRESSOR OIL ISO 32 THROUGH ISO 220, **** MATERIAL SAFETY DATA SHEET **** 22204 - STABIL Fuel Stabilizer **** SECTION 1 - CHEMICAL PRODUCT AND MANUFACTURER IDENTIFICATION ****, WINDEX ORIGINAL GLASS CLEANER WITH AMMONIA-D, Material Safety Data Sheet Ampicillin, sodium salt MSDS, =.03% CO2 10/4/2012. (To comply with OSHA s Hazard Communication Standard 29CFR 1910.1200/ANSI z400. Stainless steel pipe is reco mmended for concentrated TBC sol utions, but steel pipe lined with b aked phenolic, Teflon, or the equivalent can al so be used to reduce formation of particulate matter. 8. Tank linings have proven quite succe ssful in controlling or reducing polymer and stalactite formation. Copper and copper-containing alloys in contact with styrene must be avoided. For large r piping, butt welded fittings are preferred. Properties and health hazards of styrene. IV. (Requirements for the preceding are discussed in detail in the Styrene M onomer Storage Section of this publication.) Safe Handling Guideline 1 1.0. Storage equipment. 7. closed cup) open cup) 31 C (88 F) 37 C (98 F) Free energy of formation of gas at 25 C ( G f ) 2 Freezing point 2 Heat of combustion gas at const. All sharp ed ges and high points should be ground smooth and rounded to a minimum radius of 1/8. Product and company identification Trade name of product Product use Product dilution information : OASIS 259 GLASS FORCE : Glass Cleaner : Up to 12.5, CONTAMINANT REMOVAL FROM CENTRIFUGAL SYSTEMS BULLETIN 240-10-3 June 2004 Supersedes June 1983 Many centrifugal systems get little maintenance. Care sh ould be taken that vents, valves, pressure-relief devices, gauges, and controls do not become plugged with polymer. All references to U.S. FDA, Health Canada, and European Union regulations include another country’s equivalent regulatory classification. Take precautionary measures against static discharges. They should be fitted with closed impellers and mechanical seals. This type of co nstruction simplifies the i nstallation of linings and permits rapid drainage of uninhibited condensed vapors back into the liquid monomer, thus reducing the polymer and stalactite problem. Use only clean, oil- an d dirt-free, sparkresistant tools and implements. Revision Date: 09/08/2014 Date of issue: 09/08/2014 Version: 1.0 SECTION 1: IDENTIFICATION Product Identifier Product Form: Fabric Product Name: Oil-Only Sorbent Product Code: All M, OSW, OBW, OPW, OS, SECTION 23 81 03 - PACKAGED ROOFTOP AIR CONDITIONING UNITS NON-CUSTOM PART 1 - GENERAL 1.1 SUMMARY A. The use of insulating flanges or non-insulating hoses are recommended for marine vessel/shore connections. G. W. Jones, G. S. Scott, and W. E. Miller, Bureau of Mines Report of Investigations American Petroleum Institute Research Project 44, Selected Values of Properties of Hydrocarbons and Related Compounds. The TBC l evel should be checked at regular intervals. Paying careful attention to the oxyg en level in the styrene and in the vapor space above the styrene. Due to the nature of gas cylinders, special storage and handling precautions are necessary. Main Menu; Earn Free Access; Upload Documents; Refer Your Friends; Earn Money; Become a Tutor ; Scholarships. Emphasis should be pl aced on cl eanliness and dryness. Identification. 2 of 5. Stainless steel vessels and lines are also recommended. PRODUCT & COMPANY IDENTIFICATION Prepared on: Month, Year Manufactured, Monument Chemical bvba Johann Haltermann Ltd. Haven 1972, Ketenislaan 3 16717 Jacintoport Blvd. At this conce ntration, 1 cc of the concentrate will raise the level of inhibitor 1 ppm in a drum of styrene having a net weight of 410 pounds. Bull., 1985, (065), p. 25]. Roof and sidewall openings above the normal liquid levels in the tank should be of larg e diameter and the number kept to a minimum. If u nstable monomer is not treated promptly, it may become unsalvageable. 4 TABLE OF CONTENTS PRODUCT STEWARDSHIP POLICY...1 INTRODUCTION PART 1 PROPERTIES OF STYRENE MONOMER Physical Properties of Styrene Monomer... 3 References... 7 Typical Analysis of Americas Styrenics LLC Styrene... 8 Analytical Methods... 9 PART 2 SAMPLING AND HANDLING Training Recommended Practice for Sampling Styrene Sampling Devices Static Electricity and Grounding Product Loading/Unloading Requirements Safety References PART 3 STYRENE MONOMER STORAGE Polymerization in Storage Prevention of Polymerization Handling Runaway Polymerizations TBC Inhibitor Test Kit Inhibition Oxygen Requirements Addition of TBC to Stored Monomer Polymer Formation During Storage Color Problems Particulate Matter Drums Tanks Piping Pumps Valves Gaskets Filters Hoses O-Rings Procedure for Coating Tanks API Design References... 25, 5 PART 4 ACCIDENTAL RELEASE, FIRE AND HEALTH Accidental Release Measures Spills Disposal Fire Hazards Flammability Explosive Mixtures Fires Personal Protective Equipment and Occupational Exposure Limits Health Hazards and First Aid Environmental Hazards PART 5 TRANSPORTATION INFORMATION AND REGULATORY PROFILE Transportation Information Drums Regulatory Profile Revision Statements PART 6 APPENDIX Glossary of Terms, Abbreviations and Organizations... 36, 6 PRODUCT STEWARDSHIP POLICY Americas Styrenics LLC is committed to being a good steward of the products we produce. Table 4 list s some suppliers and specific products for the various types of coatings. All low point s should be provided with drains or some other means of rem oving the monomer. The tank should also be aera ted to provide the proper amount of dissolved oxygen. A s the liquid polymerizes and beco mes more viscous, vapor bubbles may become trapped, expanding the liquid and causing spills or rupture of the tank. In ca se material is spilled, wash contaminated areas thoroughly with large quantities of water a nd collect the liquid in the p lant chemical waste system. Sign up for the latest news on plastics and innovation! This i nformation should only be utilized in co njunction with an existing health and safety program and cannot be used as a substitute for expert safety and m edical advice. Ga te valves are less satisfactory but they are u sually less expensive and may be used. The Styrene Monomer Safe Handling Guide 2018 update has been published, as a result of several months collaborative work with the main styrene manufacturers and under the coordination of PlasticsEurope (the association that represents plastics manufacturers active in the European plastics industry, including styrene manufacturers and its derivatives). These toughened products, Industrial Process Pump Safety Manual IMPORTANT SAFETY NOTICE To: Our Valued Customers User safety is a major focus in the design of our products. The most current Material Safety Data Sheet can be obtained from Americas Styrenics by calling AMSTY (2-6789) or from the Americas Styrenics web site ( and should be carefully reviewed prior to working with this product. 100-42-5 Index No. Solution s of TBC may be obtained by contacting your Americas Styrenics LLC representative or through your purchasing agent. Storage and Handling of Flammable and Combustible Liquids. Requirements of diking, tank spaci ng, and other features pertaining to safety are detailed in guidelines set by the National Fire Protection Association (see NFPA 30). C( F) BTU/(hr.ft 2 F) 0 (32) (77) (122) (167) (212) (302) (392) JULY 2011 (PRINT), 12 REFERENCES 1. We will meet our product stewardshi p commitments through the effective implementation of our O perating Discipline Management System (ODMS). Vapor Pressure: 7mbar at 20°C: Packaging: Glass Bottle: Quantity: 1L: Vapor Density: 1.22g/mol: Refractive Index: 1.545 to 1.547 (at 20°C) Identification: Pass Test With increasing costs and tighter deadlines, the need for effective maintenance strategies is greater than ever before. SSIILLVVEERR FFEERRNN CCHHEEMMIICCAALL MMaatteerriiaall SSaaffeettyy DDaattaa SShheeeett Styrene Monomer, Stabilized _____ Effective Date: January 7, 2007 Page 1 of 11 SECTION 1: IDENTIFICATION Product Name: Styrene Monomer, Stabilized CAS Number: 100-42-5 Chemical Name: C6H5CH:CH2 Synonyms: Styrene Monomer; Vinylbenzene; … Acrylic Adhesives. SAFETY DATA SHEET According to 1907/2006/EC, Article 31 Styrene Monomer Section 1: Identification of the substance/mixture and of the company / undertaking 1.1 Product Identifier Product Name Styrene Monomer Other Names Phenylethylene CAS No. Use an approved pump to unload the tank car. - - 1/7/2008. THE USER ASSUMES ALL RISK AND LIABILITY ASSOCIATED WITH THE INFORMATION IN THIS BROCHURE. DRUMS Drums of st yrene monomer should not be permitted to stand in the sun for more than a short period of time. Packaged rooftop air conditioning unit (5 tons and smaller). The St J ames, LA plant was origina lly owned by Gulf Oil Chemical Company and has b een in operation since The plant was ISO 9000:2000 certified in 1994 with the latest recertificati on occurring in St. James has been an OSHA VPP Star site since Americas Styrenics safe and reliable operations combin ed with our market lead ing positions in styrene and polyst yrene provide a secure foundation in manufacturing logistics and customer service with which we build strong customer relationships. If unloading is interrupted, disconnect all unloading connections, close all valves tightly and securely apply all other closures. Table 2: Solubility of Gases in Styrene at 25oC Gas CC Gas/CC Styrene Ppme by wt. If either exists, they should be ground out, filled with weld metal or ep oxy putty, and g round smooth. Check carefully for leaks. See information on toxicologi cal properties and safe handling of TBC as well as manufacturer s MSDS. Totally enclo sed fan cool ed motors are recommended; however, local fire and insurance codes should be co nsulted to determine if an explosion proof motor must be used. Store in accordance with regulations for storage of flammable liquids. Avoid ingestion and inhalation. Table 4 Type of Coatings and Suppliers Inorganic Zinc Silicate 1. 3. 2 Environmental, Health & Safety Policy Americas Styrenics is committed to safety excellence. Background. An alternative is to recirculate product and inject air at a rate approximately 1-2 ft 3 /hr/million pounds of styrene monomer. Caution should be use d, however, sin ce color does not always blend proportionately. Roof curb. SAFETY REFERENCES The following publications are excellent references for styrene monomer handling information: 12 JULY 2011 (PRINT), 18 PART 3 STYRENE MONOMER STORAGE The prevention of pol ymer build-up is generally of greatest concern in the storage of styrene monomer. 2. TBC may oxidize to form highly-colored reaction products. The TBC content of styrene monomer in storage should never be allo wed to be depl eted or remain below the 10 ppm level. Chemical Product Identification Generic Name: Microcrystalline Wax INCI Name: Microcrystalline Wax Chemical Family: Mineral Emergency Telephone Numbers: Page 1, Safety Data Sheet Issue Date: 04-Oct-2013 Version Number: 1 Product Identifiers Product Name: Bright Dyes FLT Yellow/Green Liquid Product Number: 106001 Recommended Use & Restrictions on Use Water tracing. Safety Data Sheet Styrene Monomer (SM) Code : 08-002-0 Prepared By : APC Laboratory Validation Date: 03-Jan-2018 1. Americas Styrenics cares about the communities where we live and work by demonstrating a culture that puts safety above all, and heeds responsible environmental policies and practices. Cartridge type filters with a fine or medium replaceable cartridge or ba g filters are suggested. Relative Density/(Specific Gravity)2. Refer to Table 3A or 3B to determine proper amount of inhibitor to add. Internal reflux, (the vaporization and condensation due to normal temperature differentials) will dissolve small amounts of this polyme r and carry it back into the tank, thereby increasing both the polymer content and the color of the stored monomer. SECTION I- Product Information* MANUFACTURER: EPCO Carbon Dioxide Products, Inc. OFFICE PHONE: 1-800-259-3726 24-HOUR EMERGENCY: 1-800-259-8095 SHIPPING NAME: Carbon Dioxide, Refrigerated Liquid UN NUMBER: Material Safety Data Sheet:- DIHYDROGEN MONOXIDE Page No. Promp tly drain an d clean these lines after u sage. Weld ed seams need not be ground flush; however, welds should be free from undercuts or pi nholes. As a result they operate with the refrigerant highly contaminated, A Health and Safety Guideline for Your Workplace What is static electricity? does it, amend or replace the Material Safety Data Sheet for Styrene (MSDS. Chicago, IL Amercoat 346 Ameron Protective Coatings Division 201 North Berry St. Brea, CA Other equivalent or comparable coatings are undoubtedly available and may be equally satisfactory, but it would be advisable to check their resistance characteristics and obtain information on their pe rformance for this application from the m anufacturer before use. Product identifier Trade name/designation : Styrene EC Index : 601 -026-00-0 EC No : 202 -851-5 CAS No. Metal Cutting & Fabrication Product Line CHEMICAL METHODS 20338 PROGRESS DRIVE CLEVELAND, OHIO 44149 Phone: 216-476-8400 Cutting Table Corrosion Inhibitors Water table (or cutting. (1-L) glass bottle held in a clean, dry sheath of nickel or stainless steel attached to a long rod or lightweight chain of the same material. Styrene produced by Americas Styrenics is manufactured at the St. James Plant in St. James, Louisiana. 2. Acidic or highly-activated alumina may cause the styrene to polymerize. Gaskets made of rubber or oth er styrene-soluble materials should be avoided. Flammable Liquids 29 CFR 1910.106 OSHA s Directorate of Training and Education These materials were developed by OSHA s Directorate of Training and Education and are intended to assist employers, workers. Caution must be exercised in ha ndling TBC. Socket weld fittings are preferred for small connections. To use this website, you must agree to our, Air Eliminators and Combination Air Eliminators Strainers. Chem. So why not, Worldwide Contacts www.tyco-fire.com Model F thru F3 Mulsifyre Directional Spray Nozzles, Open, High Velocity General Description The Mulsifyre Nozzles are open (nonautomatic) nozzles and they are designed, Nitrogen Blanketing for Methanol Storage and Transportation Overview Air is the enemy of many materials. Store in a cool, dry well-ventilated lo cation, away from any area where the fire hazard may be acute. Box 816 Harvey, LA Modified Epoxy 1. 6. Styrene is one of the most important monomers produced by the chemical industry today. Polymerization becomes self-sustaining above 95°C [MCA SD-37, 1971]. PRODUCT AND COMPANY IDENTIFICATION turtle wax, inc 625 Willowbrook Ctr Pkwy Willowbrook, Illinois 60527 PRODUCT NAME PRODUCT CODE CHEMICAL FAMILY CHEMICAL NAME FORMULA MANUFACTURER, pdi PLASTIC DRUM INSTITUTE Plastic Drum Paneling Issues PANELING BACKGROUND This report will explain the causes of paneling and suggest some possible ways to eliminate or minimize the paneling of plastic. Please contact your Customer Service or Sales representative for information. 24 JULY 2011 (PRINT). The importance of protection from styrene contact; the proper clothing and cleaning requirements. Filter cartridges should be inspe cted and renewed periodically. Baked phenolic, modified epoxy and i norganic zinc silicates have proven satisfactory for this purpose. Can increase respiration and heart rate. 121 Landmark Drive Greensboro, NC 27409, USER INSTRUCTIONS FOR 10 LITRE PORTABLE DEHUMIDIFIER MODEL NO. Americas Styrenics will work with customers, distributors and traders to help ensure that all who use and handle our products follow safe and envir onmentally sound practices. Manufactured, Dispelling the Myths of Heat Transfer Fluids Kevin Connor The Dow Chemical Company Heat Transfer Chill Water Loop Secondary Coolant (Heat Transfer Fluid) Primary Refrigerant Expansion Device Air Handler, Eastman plasticizers Bulk storage guidelines This publication contains general information on the bulk storage of Eastman plasticizers, including guidelines for tank components and materials, as well as, TECHNIQUES FOR NATURAL GAS SAMPLING A DISCUSSION OF FIELD METHODS FOR OBTAINING SPOT SAMPLES Randall Messman SW Regional Sales Manager PGI International 16101 Vallen Drive Houston, TX 77041 Purpose Natural. Label the sample bottle according to OSHA Re gulations. Ground the tank ca r before connecting any part of it to the unloading lines or equipment. 2 JULY 2011 (PRINT), 8 PART 1 PROPERTIES OF STYRENE MONOMER PHYSICAL PROPERTIES OF STYRENE MONOMER The data contained in this section have been obtained experimentally or derived from the chemical literature referenced at the end of the section. D2340 Peroxides in Styrene Monomer 5. These will impart a green or blue-green color to the monomer and may also inhibit its polymerization. REFERENCE DOCUMENTS: ASTM D3437: Practice for Sampling and Handling Cyclic Compounds ASTM E300: Practice for Sampling In dustrial Chemicals ANSI Z : Flammable and Combustible Liquids Code API RP 500 A: Classification of Lo cations for Electrical Installations in Petroleum Refineries OSHA Regulations, 29 CFR, Pa ragraphs and U.S. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1), SECTION 1 PRODUCT AND COMPANY IDENTIFICATION Product Name : Product Code : A7804F Recommended use : E2 hand wash and sanitizer Product dilution information : Product is sold ready to use. ( C) (Centipoise) Vapor Pressure Temp. Randall Messman SW Regional Sales Manager, SECTION 2: HAZARDS IDENTIFICATION Classification of the Substance or Mixture Classification (GHS-US) Not classified, SECTION 23 81 03 - PACKAGED ROOFTOP AIR CONDITIONING UNITS NON-CUSTOM, CHAPTER 9 SAMPLERS AND SAMPLING PROCEDURES, Material Product Data Sheet Sealers for Thermal Spray Coatings, General Guidelines for Butt, Saddle, and Socket Fusion of Unlike Polyethylene Pipes and Fittings TN-13/2007, SPILL PREVENTION, CONTROL AND COUNTERMEASURE PLAN, LCT 1025 (08/08) Copyright 2008 Harleysville Mutual Insurance Company Page 1 of 5 All rights reserved, Compressed Gas Cylinder Storage and Handling Guide, FLAMMABLE AND COMBUSTIBLE LIQUIDS.